Returns the exterior ring of a Polygon. This function extracts the outer boundary of the polygon as a LineString geometry.
SET @poly = 'Polygon((0 0,0 3,3 3,3 0,0 0),(1 1,1 2,2 2,2 1,1 1))';
SELECT AsText(ExteriorRing(GeomFromText(@poly)));
+-------------------------------------------+
| AsText(ExteriorRing(GeomFromText(@poly))) |
+-------------------------------------------+
| LINESTRING(0 0,0 3,3 3,3 0,0 0) |
+-------------------------------------------+