Returns the combinatorial boundary of a geometry. For a Polygon, this is the line string defining the boundary.
SELECT ST_AsText(ST_Boundary(ST_GeomFromText('LINESTRING(3 3,0 0, -3 3)')));
+----------------------------------------------------------------------+
| ST_AsText(ST_Boundary(ST_GeomFromText('LINESTRING(3 3,0 0, -3 3)'))) |
+----------------------------------------------------------------------+
| MULTIPOINT(3 3,-3 3) |
+----------------------------------------------------------------------+
SELECT ST_AsText(ST_Boundary(ST_GeomFromText('POLYGON((3 3,0 0, -3 3, 3 3))')));
+--------------------------------------------------------------------------+
| ST_AsText(ST_Boundary(ST_GeomFromText('POLYGON((3 3,0 0, -3 3, 3 3))'))) |
+--------------------------------------------------------------------------+
| LINESTRING(3 3,0 0,-3 3,3 3) |
+--------------------------------------------------------------------------+